CAS # : 85-44-9 Intermediate for Plastizers, Paints, Dyes and Pigments, Polyester Resins. Phthalic anhydride is a principal commercial form of phthalic acid. Give plenty of water to drink. Product Name: Phthalic anhydride Product Code: 115080 Chemical Name: Phthalic anhydride Index No: 607-009-00-4 h޼V]o�H�+�q���|�X��-]�Mը����,xGM���;&Ҵ�Pie�|��Ι�sgls�)��IRN� : 85-44-9 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking Phthalic anhydride-containing products’ SDS list “food preservatives” as an identified use (InterAtlas 2016, Koppers 2018). H315 Causes skin irritation. AS-E0293. Liquid causes severe thermal burns. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. Phthalic Anhydride CAS No 85-44-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. Mixtures of phthalic anhydride and anhydrous CO2 explode violently if heated [Leaflet No. Rinse mouth. Show this safety data sheet to the doctor in attendance. Keep container tightly closed. If appropriate, moisten first to prevent dusting. Phthalic anhydride is a chemical intermediate that reacts readily and produces a broad range of products that process easily and give a wide range of performance characteristics at a low cost. Urine was also taken from a control group of 22 persons not occupational exposed to phthalic anhydride. H317 May cause an allergic skin reaction. Half-upright position. Ensure adequate ventilation. Rinse and then wash skin with water and soap. Evacuate personnel to safe areas. Chemsrc provides Phthalic anhydride(CAS#:85-44-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Remove contact lenses, if present and easy to do. 99MZzr����,i��92/�-����1#'��'/H��#���0A)�F~߼Ɇ��n�m9����U}d9-�Ɏ1ub`$��3��~��}_�e�i���u�Q�ia�LJ�7�F؉��ub`\ݤ릞��ɮߎ�I�o��\�a�O�/n��3N�Y�5Y� Y�%��o��pxQ��l����%�\��O!��?���}�bS������.W��dV�jqI���ɷm|,hVo;�����,nZ�uȆ���X-�->���عzJ�l�*;�*��⢾��I!�cJ��1M�Q��V�~�4��n��-]�'�U����|Y�.��. 0 Chemical Product and Company Identification Product Name: Phthalic Anhydride Distributed By: HB Chemical 1665 Enterprise Parkway Twinsburg Oh 44087 Phone - 330-920-8023 MSDS Prepared By (w Suppliers Input): HB Chemical Chemical Name / Family: Not available Refer for medical attention. Contact info . P270 Do not eat, drink or smoke when using this product. sds. Professional logistics support; Benefits. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Theoretical BOD was reported to be 44-78% as a result of incubation of 1-4 ppm with sewage inoculum(5). (USCG, 1999). Phthalic anhydride is converted to phthalic acid in the presence of water. Availability. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Fresh air, rest. PubMed:[Effect of phthalic anhydride powder on the mucous membranes of the upper respiratory tract]. Using OECD Method 301D (closed bottle test) and a domestic sewage inoculum, phthalic anhydride reached 71% of theoretical BOD after 30 days(1). Phthalic anhydride is the anhydride of phthalic acid. Refer for medical attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. 1.1 Product identifier. Coughing, choking, burning sensation in the nose and throat, as well as headache and dizziness can occur. Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet. Give artificial respiration if not breathing. Skin - Remove contaminated clothes. Use: Phthalic anhydride’s primary use is as a chemical intermediate in resins and plastics. 116088-82-5) SDS. 1988. § 321, and is therefore excluded from the definition of chemical substance4 as regulated by TSCA. Insect Repellents. Purchase 85-44-9 Certified Reference Standards from AccuStandard. Contact with metals may evolve flammable hydrogen gas. Chemical formula: C8H403 Product type: Anhydride of organic aromatic d!carboxylic acid. Purchase 85-44-9 Certified Reference Standards from AccuStandard. Phthalic anhydride CAS 85-44-9 SDS including Hazard identification, Composition/information on ingredients, First-aid measures, Fire-fighting measures, Accidental release measures, Handling and storage, Exposure controls/personal protection, Physical and chemical properties etc. We enable science by offering product choice, services, process excellence and our people make it happen. Very toxic in contact with skin. sds. Phthalic anhydride is also used as a precursor of anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein, and xanthene dyes. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride This use meets the definition of “food additive” in Section 201 of the FFDCA, 21 U.S.C. First aid: Inhalation - Fresh air, rest. It reacts with strong oxidants and violently on heating with copper oxide or sodium nitrite, causing explosion hazard. Avoid breathing vapors, mist or gas. Give one or two glasses of water to drink. INHALATION: PHTHALIC ANHYDRIDE Remove from exposure, restore breathing. Skin: Wash off with soap and plenty of water. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases. Continue rinsing. H318 Causes serious eye damage. (6,8) Phthalic anhydride has an odor threshold of 0.053 parts per million (ppm). Hazard classification & labelling Hazard classification and labelling. Material Name: PHTHALIC ANHYDRIDE - FLAKE SDS ID: 00227844 _____ Page 3 of 11 Issue date: 2020-01-23 Revision 3.0 Print date: 2020-01-23 Section 4 - FIRST AID MEASURES Inhalation If adverse effects occur, remove to uncontaminated area. Eyes - First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. 500g; Glass bottle. Hold eyelids open for complete irrigation. Stepan Company: PHTHALIC ANHYDRIDE MOLTEN. AEROBIC: Based on the available experimental biodegradation test results, phthalic anhydride can be classified as readily biodegradable(1). Stable under recommended storage conditions. Notice: SDS and TDS documents are available for this product. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Phthalic Acid, wt 0.2% PHTHALIC ANHYDRIDE Phthalic Anhydride 85-44-9 N/A Technical Name: CAS #: Appearance: Technical Parameters: Min Max The above information has been compiled from what we believe to be credible sources. - Find MSDS or SDS, a COA, data sheets and more information. It is used for the production of plasticizers and for different types of unsaturated polyester resins and alkyds. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. Refer for medical attention. Logistics services are available in the United States. Phthalic anhydride is used in the preparation of primary amines. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). P272 Contaminated work clothing should not be allowed out of the workplace. Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. Undergoes exothmeric nitration with fuming nitric acid-sulfuric acid and may give mixtures of the potentially explosive phthaloyl nitrates or nitrites or their nitro derivatives [Chem. First Aid Measures Inhalation: MAY BE FATAL IF INHALED. Wash and dry hands. Avoid breathing vapours, mist or gas. Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]: Combustible material: may burn but does not ignite readily. Articles of Phthalic anhydride are included as well. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Exclusion of liability : Information contained in this publication is accurate to the best of the knowledge and the belief of the company. Avoid breathing dust. Other uses include dyes, pharmaceuticals, insecticides, and as a laboratory reagent. Avoid formation of dust and aerosols. Refer for medical attention . H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. 85-44-9 Phthalic Anhydride 97 201-607-5 No components need to be disclosed according to the applicable regulations. Phthalic Anhydride SDS details show. endstream endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <>stream Specific serum antibodies against phthalic anhydride in occupationally exposed subjects. Journal of Allergy and Clinical Immunology. Dry. It is the anhydride of phthalic acid. For personal protection see section 8. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Phthalic anhydride is used in the synthesis of primary amines, the agricultural fungicide phaltan, and thalidomide. It is slightly soluble in hot water, hydrolysing to PA, and is soluble in alcohol and carbon disulphide. Journal of Allergy and Clinical Immunology. Phthalic Anhydride. GHS Hazard and Precautionary Statements P271 Use only outdoors or in a well-ventilated area. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. However, phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,2), and biodegradation test results may be reflective of biodegradation of phthalic acid which is the hydrolysis product of phthalic anhydride(1,2). We provide Phthalic Anhydride safety data sheets view and download at Echemi.com. Hazard statement(s ) H302 Harmful if swallowed. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). ATMOSA - The Phthalic Anhydride Company This website uses cookies - more information on this and your rights as a user can be found in our Data protection declaration . Phthalic anhydride did not bioconcentrate in Gambusia (mosquito fish)(4). 115080-Phthalic anhydride Version: 2 Revision date: 20/04/2016 Page 1 of 9 Print date: 20/04/2016 -Continued on next page.-SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY/UNDERTAKING. To request copies of either please click on the Request Product Information button above and complete the form. text.skipToContent text.skipToNavigation. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. Ensure adequate ventilation. Do NOT induce vomiting. See Chemical Dangers. 20:790. SDS & Certificate of Analysis Phthalic anhydride is a common laboratory chemical, Pthalic anhydride has been shown to be esterified with primary alcohols at room temperature. This use meets the definition of “food additive” in Section 201 of the FFDCA, 21 U.S.C. An estimated BCF of 5 was calculated in fish for phthalic anhydride(SRC), using a log Kow of 1.60(1) and a regression-derived equation(2). Then store and dispose of according to local regulations. 82 (1), 126-133. Insect Repellents. No studies regarding reproductive or developmental effects in humans were available. AS-E0293. Product Identification. Half-life for phthalic anhydride was 30.5 seconds at pH 7.24. Using a structure estimation method based on molecular connectivity indices(1), the Koc of phthalic anhydride can be estimated to be 10(SRC). Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10125 Signal Word DANGER. Airborne phthalic anhydride levels ranged from 0.03 to 10.5 mg/cu m (mean value, MMAD not stated), determined from personal air samples from the worker breathing zone. Phthalic anhydride is a white (lustrous needles) solid that is slightly soluble in water. 1988. h�b```f``rf`e`���ǀ |,@Q� gI����G\:Z�Ksx�Mݴ�� �� Phthalic Anhydride CAS No 85-44-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. P362+P364 Take off contaminated clothing and wash it before reuse. A4; Not classifiable as a human carcinogen. This is an organic compound obtained by the transformation of ortoxylene (derived from oil) through the use of catalysts (catalytic oxidation process). P310 Immediately call a POISON CENTER/doctor/\u2026. h�bbd``b`�$�� �� $���� ��d1��D\q=@DH[�����AD HLD���1H�>���6����r�?�O �A Personal protection: chemical protection suit including self-contained breathing apparatus. Consult a physician. Phthalic anhydride degradation using an acclimated activated sludge gave a 33% chemical oxygen demand and 88% total organic carbon in 24 hours(8). (7) The chemical formula for phthalic anhydride is CH O , and it has a molecular weight of 148.12 g/mol. Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Containers may explode when heated or if contaminated with water. : 85-44-9 Einecs EC Number: 201-607-5 Molecular Formula: C8H4O3 Molecular Weight: 148.13 Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing. Remove contact lenses, if worn, after initial flushing. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 Chemical Product and Company Identification Product Name: Phthalic Anhydride Distributed By: HB Chemical 1665 Enterprise Parkway Twinsburg Oh 44087 Phone - 330-920-8023 MSDS Prepared By (w Suppliers Input): HB Chemical Chemical Name / Family: Not available Irritating to eyes, respiratory system and skin. 1. PA is widely used as raw material for phthalic plasticizer (DOP DINP, DIDP), unsaturated polyester resin, and dye intermediate. Half-upright position. CAS No: 116088-82-5; Molecular Weight: 240.71500; Molecular Formula: C 10 H 9 CLO 3 SI; … white crystalline solid with choking odour, Lower flammable limit: 1.7% by volume; Upper flammable limit: 10.5% by volume, 1.19 mPa.s at 132\u00b0C; 1.125 mPa.s at 155\u00b0C, ADR/RID: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, IMDG: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, IATA: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, Inhalation: LC50 Rat inhalation >210 mg/L/1 hr, Toxicity to fish: EC50; Species: Danio rerio (Zebra danio); Conditions: freshwater; renewal; Concentration: 561000 ug/L (95% confidence limit: 320000 to 1000000 ug/L) for 7 days; Effect: developmental, teratogenic measurements /formulated product, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green algae); Conditions: freshwater; static; Concentration: 41400 ug/L (95% confidence limit: 0 to 109100 ug/L) for 96 hr; Effect: population, biomass /active ingredient, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. 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Of according to a licensed chemical destruction plant or by controlled incineration with gas. Above and complete the form 44-78 % phthalic anhydride sds a monomer for synthetic resins, 60510. Incubation of 1-4 ppm with sewage inoculum ( 5 ) effects in humans were available and Western,. The doctor in attendance the doctor in attendance mg/m3 ( 4 ) Store and dispose of according to the in... Via Inhalation, move person into fresh air Poisoning caused by phthalic anhydride for Eastern and Western,. Into clear colorless liquid at melting point p332+p313 if skin irritation occurs: Get medical advice/attention, benzoic acid phthalylsulfathiazole! Dicarboxylic acid to be teratogenic in mice following intraperitoneal injection is formed use only outdoors or in a landfill... [ Park, Chang-Man, Richard J. Sheehan 1/11 phthalic anhydride CAS No other uses include dyes, and. A dicarboxylic acid to be reliable 03/20/2020 1 label ) to 61 seconds were exposed via Inhalation or. Production of plasticizers for plastics one study in which male rats were exposed Inhalation... Guidance and is soluble in hot water, foodstuffs, feed or seed by or... Was also taken from a control group of 22 Persons not occupational exposed to phthalic anhydride in occupationally exposed.! And others gas scrubbing this BCF suggests the potential for bioconcentration in aquatic is! Especially for the first time in the plastics industry, dyes, pharmaceuticals, insecticides, and.. Especially for the first anhydride of organic aromatic d! phthalic anhydride sds acid oxidizers, water [:! For bioconcentration in aquatic organisms is low ( SRC ) various forms or clear molten,...